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Keywords: stereoselectivity
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Biochem J (2003) 373 (1): 33–40.
Published: 01 July 2003
... with the catalytic potential of AChE. To analyse the constraints on stereoselective phosphonylation, the mutant enzymes were reacted with a congeneric series of S P - and R P -methylphosphonates of known absolute stereochemistry. Where possible, the overall reaction rates were deconstructed into the primary...
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